cmd.exe and at the prompt, add the PuTTY directory your search path:
set PATH=%PATH%;"C:\Program Files\PuTTY"
pscp [[-r]] -i key.ppk source ubuntu@ec2-public-hostname:dest
key.ppk is the path to the private key you exported and saved when first logging in. ec2-public-hostname is the Public Hostname of your master node. source is the local file or folder you want to copy, and dest is the target filename on the EC2 node. Use the -r option if you are copying a directory.